It is not possible to drag and drop the "Subsites" picker when configuring a content type's field order. The item isn't available in the list to drag and drop.

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davyvdb’s picture

davyvdb commented
Status: Active » Closed (won't fix)

That's because it is not a real field (and not part of the content array). Some other module might do this for you http://drupal.org/project/nodeform, http://drupal.org/project/node_form_rearrange, http://drupal.org/project/nodeformcols or you could always fall back on hook_form_alter in your own module.